Mixed‐Organic‐Cation Tin Iodide for Lead‐Free Perovskite Solar Cells with an Efficiency of 8.12%

نویسندگان

  • Ziran Zhao
  • Feidan Gu
  • Yunlong Li
  • Weihai Sun
  • Senyun Ye
  • Haixia Rao
  • Zhiwei Liu
  • Zuqiang Bian
  • Chunhui Huang
چکیده

In this work, a fully tin-based, mixed-organic-cation perovskite absorber (FA) x (MA)1-x SnI3 (FA = NH2CH = NH2+, MA = CH3NH3+) for lead-free perovskite solar cells (PSCs) with inverted structure is presented. By optimizing the ratio of FA and MA cations, a maximum power conversion efficiency of 8.12% is achieved for the (FA)0.75(MA)0.25SnI3-based device along with a high open-circuit voltage of 0.61 V, which originates from improved perovskite film morphology and inhibits recombination process in the device. The cation-mixing approach proves to be a facile method for the efficiency enhancement of tin-based PSCs.

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عنوان ژورنال:

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2017